WSU Physicists Write With Light, Turn Crystal Into an Electrical Circuit

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Washington State University physicists have found a way to write an electrical circuit into a crystal, opening up the possibility of transparent, three-dimensional electronics that, like an Etch-A-Sketch, can be erased and reconfigured.

WSU researchers used light to write a highly conducting electric path in a crystal. This opens up the possibility of transparent, three-dimensional electronics that, like an Etch-A-Sketch, can be erased and reconfigured. On the left, a photograph of a sample with four metal contacts. On the right, an illustration of a laser drawing a conductive path between two contacts. Credit: Washington State University

The work, to appear in the on-line journal Scientific Reports, serves as a proof of concept for a phenomenon that WSU researchers first discovered by accident four years ago. At the time, a doctoral student found a 400-fold increase in the electrical conductivity of a crystal simply by leaving it exposed to light.

Matt McCluskey, a WSU professor of physics and materials science, has now used a laser to etch a line in the crystal. With electrical contacts at each end of the line, it carried a current.

“It opens up a new type of electronics where you can define a circuit optically and then erase it and define a new one,” said McCluskey. “It’s exciting that it’s reconfigurable. It’s also transparent. There are certain applications where it would be neat to have a circuit that is on a window or something like that, where it actually is invisible electronics.”

Ordinarily, a crystal does not conduct electricity. But when the crystal strontium titanate is heated under the right conductions, it is altered so light will make it conductive. The phenomenon, called “persistent photoconductivity,” also occurs at room temperature. This makes it easier to improve conductivity than cooling materials with liquid nitrogen, another focus of research.

“We’re still trying to figure out exactly what happens,” said McCluskey. He surmises that heat forces strontium atoms to leave the material, creating light-sensitive defects responsible for the persistent photoconductivity.

McCluskey’s recent work increased the crystal’s conductivity 1,000-fold. The phenomenon can last up to a year.

“We look at samples that we exposed to light a year ago and they’re still conducting,” said McCluskey. “It may not retain 100% of its conductivity, but it’s pretty big.”

Moreover, the circuit can be by erased by heating it on a hot plate and recast with an optical pen.

“It’s an Etch-A-Sketch,” said McCluskey. “We’ve done it a few cycles. Another engineering challenge would be to do that thousands of times.”

The research was funded by the National Science Foundation. Co-authors on the paper are former students Violet Poole and Slade Jokela.

The work is in keeping with WSU’s Grand Challenges, a suite of initiatives aimed at addressing large societal problems. It is particularly relevant to the challenge of Smart Systems and its theme of foundational and emergent materials.