Nanoworld 'Snow Blowers' Carve Straight Channels in Semiconductor Surfaces

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In the nanoworld, tiny particles of gold can operate like snow blowers, churning through surface layers of an important class of semiconductors to dig unerringly straight paths. The surprising trenching capability, reported by scientists from the National Institute of Standards and Technology (NIST) and IBM, is an important addition to the toolkit of nature-supplied “self-assembly” methods that researchers aim to harness for making useful devices.

Foreseeable applications include integrating lasers, sensors, wave guides and other optical components into so-called lab-on-a-chip devices now used for disease diagnosis, screening experimental materials and drugs, DNA forensics and more. Easy to control, the new gold-catalyzed process for creating patterns of channels with nanoscale dimensions could help to spawn entirely new technologies fashioned from ensembles of ultra-small structures.

Preliminary research results that began as lemons—a contaminant-caused failure that impeded the expected formation of nanowires—eventually turned into lemonade when scanning electron microscope images revealed long, straight channels.

“We were disappointed, at first,” says NIST research chemist Babak Nikoobakht. “Then we figured out that water was the contaminant in the process—a problem that turned out to be a good thing.”

That’s because, as determined in subsequent experiments, the addition of water vapor served to transform gold nanoparticles into channel diggers, rather than the expected wire makers. Beginning with studies on the semiconductor indium phosphide, the team teased out the chemical mechanisms and necessary conditions underpinning the surface-etching process.

First, they patterned the surface of the semiconductor by selectively coating it with a gold layer only a few nanometers thick. Upon heating, the film breaks up into tiny particles that become droplets. The underlying indium phosphide dissolves into the gold nanoparticles above, creating a gold alloy. Then, heated water vapor is introduced into the system. At temperatures below 300 degrees Celsius (572 degrees Fahrenheit), the tiny gold-alloy particles, now swathed with water molecules, etch nanoscale pits into the indium phosphide.

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