Scientists Design Promising New Cathode for Sodium-based Batteries
July 21, 2017 | BNLEstimated reading time: 3 minutes
Scientists have designed a new type of cathode that could make the mass production of sodium batteries more feasible. Batteries based on plentiful and low-cost sodium are of great interest to both scientists and industry as they could facilitate a more cost-efficient production process for grid-scale energy storage systems, consumer electronics and electric vehicles. The discovery was a collaborative effort between researchers at the Institute of Chemistry (IOC) of Chinese Academy of Sciences (CAS) and the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory.
Xiao-Qing Yang (left) and Enyuan Hu (center) of Brookhaven's Chemistry Department, pictured with beamline physicist Eli Stavitski (right) at the ISS beamline at NSLS-II.
Lithium batteries are commonly found in consumer electronics such as smartphones and laptop computers, but in recent years, the electric vehicle industry also began using lithium batteries, significantly increasing the demand on existing lithium resources.
“Just last year, the price of lithium carbonate tripled, because the Chinese electric vehicle market started booming,” said Xiao-Qing Yang, a physicist at the Chemistry Division of Brookhaven Lab and the lead Brookhaven researcher on this study.
In addition, the development of new electrical grids that incorporate renewable energy sources like wind and solar is also driving the need for new battery chemistries. Because these energy sources are not always available, grid-scale energy storage systems are needed to store the excess energy produced when the sun is shining and the wind is blowing.
Scientists have been searching for new battery chemistries using materials that are more readily available than lithium. Sodium is one of the most desirable options for researchers because it exists nearly everywhere and is far less toxic to humans than lithium.
But sodium poses major challenges when incorporated into a traditional battery design. For example, a typical battery’s cathode is made up of metal and oxygen ions arranged in layers. When exposed to air, the metals in a sodium battery’s cathode can be oxidized, decreasing the performance of the battery or even rendering it completely inactive.
The researchers at IOC of CAS and Jiangxi Normal University sought to resolve this issue by substituting different types of metals in the cathode and increasing the space between these metals. Then, using the Inner-Shell Spectroscopy (ISS) beamline at Brookhaven’s National Synchrotron Light Source II (NSLS-II)—a DOE Office of Science User Facility—Brookhaven’s researchers compared the structures of battery materials with unsubstituted materials to these new battery materials with substitute metals.
“We use the beamline to determine how metals in the cathode material change oxidation states and how it correlates with the efficiency and lifetime of the battery’s structure,” says Eli Stavitski, a physicist at the ISS beamline.”
The ISS beamline was the first operational x-ray spectroscopy beamline at NSLS-II. Here, researchers shine an ultra-bright x-ray beam through materials to observe how light is absorbed or reemitted. These observations allow researchers to study the structure of different materials, including their chemical and electronic states.
The ISS beamline, which is specifically designed for high-speed experiments, allowed the researchers to measure real-time changes in the battery during the charge-discharge processes. Based on their observations made at the beamline, Brookhaven’s team discovered that oxidation was suppressed in the sodium batteries with substituted metals, indicating the newly designed sodium batteries were stable when exposed to air. This is a major step forward in enabling future mass production of sodium batteries.
The researchers say this study is the first of many that will use the ISS beamline at NSLS-II to advance the study of batteries.
This study was supported by several Chinese research organizations, including the National Key R&D Program of China. The work at Brookhaven National Laboratory was supported by DOE’s Office of Energy Efficiency and Renewable Energy, the Vehicle Technology Office under Advanced Battery Material Research (BMR). DOE’s Office of Science (BES) also supports operations at NSLS-II.
Brookhaven National Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov.
Testimonial
"We’re proud to call I-Connect007 a trusted partner. Their innovative approach and industry insight made our podcast collaboration a success by connecting us with the right audience and delivering real results."
Julia McCaffrey - NCAB GroupSuggested Items
September 2025 PCB007 Magazine: The Future of Advanced Materials
09/16/2025 | I-Connect007 Editorial TeamMoore’s Law is no more, and the advanced material solutions being developed to grapple with this reality are surprising, stunning, and perhaps a bit daunting. Buckle up for a dive into advanced materials and a glimpse into the next chapters of electronics manufacturing.
I-Connect007 Launches Advanced Electronics Packaging Digest
09/15/2025 | I-Connect007I-Connect007 is pleased to announce the launch of Advanced Electronics Packaging Digest (AEPD), a new monthly digital newsletter dedicated to one of the most critical and rapidly evolving areas of electronics manufacturing: advanced packaging at the interconnect level.
Panasonic Industry will Double the Production Capacity of MEGTRON Multi-layer Circuit Board Materials Over the Next Five Years
09/15/2025 | Panasonic Industry Co., Ltd.Panasonic Industry Co., Ltd., a Panasonic Group company, announced plans for a major expansion of its global production capacity for MEGTRON multi-layer circuit board materials today. The company plans to double its production over the next five years to meet growing demand in the AI server and ICT infrastructure markets.
Trouble in Your Tank: Implementing Direct Metallization in Advanced Substrate Packaging
09/15/2025 | Michael Carano -- Column: Trouble in Your TankDirect metallization systems based on conductive graphite are gaining popularity throughout the world. The environmental and productivity gains achievable with this process are outstanding. Direct metallization reduces the costs of compliance, waste treatment, and legal issues related to chemical exposure. A graphite-based direct plate system has been devised to address these needs.
Fresh PCB Concepts: Designing for Success at the Rigid-flex Transition Area
08/28/2025 | Team NCAB -- Column: Fresh PCB ConceptsRigid-flex PCBs come in all shapes and sizes. Manufacturers typically use fire-retardant, grade 4 (FR-4) materials in the rigid section and flexible polyimide materials in the flex region. Because of the small size, some rigid-flex PCBs, like those for hearing aid devices, are among the most challenging to manufacture. However, regardless of its size, we should not neglect the transition area between the rigid and flexible material.