Nano-chimneys Can Cool Circuits
January 5, 2017 | Rice UniversityEstimated reading time: 2 minutes
A few nanoscale adjustments may be all that is required to make graphene-nanotube junctions excel at transferring heat, according to Rice University scientists.
The Rice lab of theoretical physicist Boris Yakobson found that putting a cone-like “chimney” between the graphene and nanotube all but eliminates a barrier that blocks heat from escaping.
Heat is transferred through phonons, quasiparticle waves that also transmit sound. The Rice theory offers a strategy to channel damaging heat away from next-generation nano-electronics.
Both graphene and carbon nanotubes consist of six-atom rings, which create a chicken-wire appearance, and both excel at the rapid transfer of electricity and phonons.
But when a nanotube grows from graphene, atoms facilitate the turn by forming heptagonal (seven-member) rings instead. Scientists have determined that forests of nanotubes grown from graphene are excellent for storing hydrogen for energy applications, but in electronics, the heptagons scatter phonons and hinder the escape of heat through the pillars.
The Rice researchers discovered through computer simulations that removing atoms here and there from the two-dimensional graphene base would force a cone to form between the graphene and the nanotube. The geometric properties (aka topology) of the graphene-to-cone and cone-to-nanotube transitions require the same total number of heptagons, but they are more sparsely spaced and leave a clear path of hexagons available for heat to race up the chimney.
“Our interest in advancing new applications for low-dimensional carbon — fullerenes, nanotubes and graphene — is broad,” Yakobson said. “One way is to use them as building blocks to fill three-dimensional spaces with different designs, creating anisotropic, nonuniform scaffolds with properties that none of the current bulk materials have. In this case, we studied a combination of nanotubes and graphene, connected by cones, motivated by seeing such shapes obtained in our colleagues’ experimental labs.”
The researchers tested phonon conduction through simulations of free-standing nanotubes, pillared graphene and nano-chimneys with a cone radius of either 20 or 40 angstroms. The pillared graphene was 20 percent less conductive than plain nanotubes. The 20-angstrom nano-chimneys were just as conductive as plain nanotubes, while 40-angstrom cones were 20 percent better than the nanotubes.
“The tunability of such structures is virtually limitless, stemming from the vast combinatorial possibilities of arranging the elementary modules,” said Alex Kutana, a Rice research scientist and co-author of the study. “The actual challenge is to find the most useful structures given a vast number of possibilities and then make them in the lab reliably.
“In the present case, the fine-tuning parameters could be cone shapes and radii, nanotube spacing, lengths and diameters. Interestingly, the nano-chimneys also act like thermal diodes, with heat flowing faster in one direction than the other,” he said.
Rice graduate student Ziang Zhang is lead author of the paper. Ajit Roy, a principal materials research engineer at the Air Force Research Laboratory in Dayton, Ohio, is a co-author. Yakobson is the Karl F. Hasselmann Professor of Materials Science and NanoEngineering and a professor of chemistry.
Suggested Items
IDTechEx Discusses Low-Loss Materials: The Enabler of Future Connected Vehicles?
05/06/2024 | IDTechExFuture connected vehicles will offer future drivers a safer, smoother, and more convenient driving experience. Not only will drivers get access to more navigation and entertainment options, but they will also gain access to safety technologies that will potentially reduce accidents, improve congestion, and reduce emissions globally by allowing vehicle safety systems to communicate with each other and with city traffic infrastructure.
LQDX Divests Aluminum Soldering Business - Mina™ - to Taiyo America Inc.
05/02/2024 | PRNewswireLQDX, formerly known as Averatek Corp., developer of high-performance materials for advanced semiconductor manufacturing, today announced that it has divested its aluminum soldering business – known as MinaTM – to Taiyo America Inc., a global market leader in advanced electronic materials.
Indium Corporation Expert to Present on Pb-Free Solder for Die-Attach in Discrete Power Applications
04/30/2024 | Indium CorporationIndium Corporation Product Manager – Semiconductor Dean Payne will present at the Advanced Packaging for Power Electronics conference, hosted by IMAPS, held May 8-9 in Woburn, Massachusetts, USA.
Real Time with... IPC APEX EXPO 2024: Adhesive Materials and Equipment Update with Dymax
05/01/2024 | Real Time with...IPC APEX EXPOVirginia Hogan, global business development manager at Dymax, discusses adhesive materials, dispensing and curing equipment, a new, high-reliability conformal coating, and various materials and dispensing methods.
Real Time with... IPC APEX EXPO 2024: Sustainability in the Industry
04/26/2024 | Real Time with...IPC APEX EXPOGuest Editor Henry Crandall and Chris Nash of Indium Corporation discuss the company's 90th anniversary and its focus on sustainability. They focus on the benefits of sustainable materials, their compatibility, and value propositions. The conversation also highlights how Durafuse LT technology's role in reducing reflow temperatures is leading to significant cost and energy savings. Nash also touches on downstream sustainability efforts such as using recycled materials for packaging.