Flexible Circuit Materials for High-Temperature Applications
June 9, 2015 | Sidney Cox, DuPont Circuit and Packaging MaterialsEstimated reading time: 1 minute

Abstract
Many opportunities exist for flexible circuits in high-temperature applications (automotive, military, aerospace, oil and gas). Flex circuits in these applications have been hindered by a lack of materials that can survive higher temperatures. Some materials, especially some thermoset adhesives, break down over time at higher temperature, becoming brittle or losing adhesion to copper. Polyimides tend to perform much better under high temperature.
The other issue is the lack of good test methods to verify that flex materials can survive higher temperatures. Several methods for testing copper clad laminates exist, but there are very few for coverlays and bondplies. We will discuss different test methods for measuring high-temperature capability including the new IPC service temperature test. We will also report on test results for various flexible materials and our recommendations for the best flexible materials for high temperature applications. This will include development work on new flex materials for high-temperature applications.
Introduction
More applications require flexible circuits that must survive high-temperature environments. These include automotive applications near the engine, oil and gas down-hole pumps, and aerospace applications near jet engines. There have been limited test methods to determine what temperatures flexible materials can survive.
The damage caused by high-temperature environments will mainly fall in three categories: loss of adhesion between copper and dielectric, loss of adhesion between dielectric layers, and embrittlement of the dielectric layers. At the highest temperatures the copper would also become brittle, but in most cases the flexible circuit dielectrics fail first. Thermoset adhesives seem to be most sensitive to embrittlement especially compared to polyimide films which are much more resistant to high temperatures.
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Editor's Note: This article originally appeared in the June 2015 issue of The PCB Magazine.
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