The material they ended up with is highly transparent, which could make it useful for de-icing car windshields, says Grossman, the Morton and Claire Goulder and Family Professor in Environmental Systems and a professor of materials science and engineering. While many cars already have fine heating wires embedded in rear windows for that purpose, anything that blocks the view through the front window is forbidden by law, even thin wires. But a transparent film made of the new material, sandwiched between two layers of glass — as is currently done with bonding polymers to prevent pieces of broken glass from flying around in an accident — could provide the same de-icing effect without any blockage. German auto company BMW, a sponsor of this research, is interested in that potential application, he says.
With such a window, energy would be stored in the polymer every time the car sits out in the sunlight. Then, “when you trigger it,” using just a small amount of heat that could be provided by a heating wire or puff of heated air, “you get this blast of heat,” Grossman says. “We did tests to show you could get enough heat to drop ice off a windshield.” Accomplishing that, he explains, doesn’t require that all the ice actually be melted, just that the ice closest to the glass melts enough to provide a layer of water that releases the rest of the ice to slide off by gravity or be pushed aside by the windshield wipers.
The team is continuing to work on improving the film’s properties, Grossman says. The material currently has a slight yellowish tinge, so the researchers are working on improving its transparency. And it can release a burst of about 10 degrees Celsius above the surrounding temperature — sufficient for the ice-melting application — but they are trying to boost that to 20 degrees.
Already, the system as it exists now might be a significant boon for electric cars, which devote so much energy to heating and de-icing that their driving ranges can drop by 30 percent in cold conditions. The new polymer could significantly reduce that drain, Grossman says.
“The approach is innovative and distinctive,” says Sargent, from the University of Toronto. “The research is a major advance towards the practical application of solid-state energy-storage/heat-release materials from both a scientific and engineering point of view.”
The work was supported by a NSERC Canada Banting Fellowship and by BMW.